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BS EN 71-5:2015 – TC:2020 Edition

$280.87

Tracked Changes. Safety of toys – Chemical toys (sets) other than experimental sets

Published By Publication Date Number of Pages
BSI 2020 200
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This European Standard specifies requirements and test methods for the substances and materials used in chemical toys (sets) other than experimental sets. These substances and mixtures are: ? those classified as dangerous by the EC-legislation applying to dangerous substances and dangerous mixtures [5]; ? substances and mixtures which in excessive amounts could harm the health of the children using them and which are not classified as dangerous by the above mentioned legislation; and ? any other chemical substance(s) and mixture(s) delivered with the chemical toy. NOTE The terms “substance” and “ mixture” are defined in the REACH regulation No. (EC)1907/2006 and in the CLP regulation (EC) No. 1272/2008. Additionally, requirements are specified for markings, warnings, safety rules, contents list, instructions for use and first aid information. This Part of EN 71 applies to: ? plaster of Paris (gypsum) moulding sets; ? ceramic and vitreous enamelling materials supplied in miniature workshop sets; ? oven-hardening plasticised PVC modelling clay sets; ? plastic moulding sets; ? embedding sets; ? adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents), supplied or recommended in model sets.

PDF Catalog

PDF Pages PDF Title
126 1 Scope
2 Normative references
127 3 Terms and definitions
128 4 Plaster of Paris (gypsum) moulding sets
4.1 Marking
4.2 First aid information
4.3 Safety rules
129 5 Oven-hardening plasticised PVC modelling clay sets
5.1 Chemical substances
5.2 Marking
5.3 First aid information
130 5.4 Safety rules
6 Moulding sets
6.1 Polystyrene granules sets
6.1.1 Chemical substances
6.1.2 Marking
6.1.3 First aid information
131 6.1.4 Safety rules
6.2 Embedding sets
6.2.1 General
6.2.2 Packaging
6.2.3 Marking
6.2.4 First aid information
6.2.5 Safety rules
132 7 Adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) supplied or recommended in model sets
7.1 General
7.2 Adhesives
7.2.1 Water-based adhesives
7.2.1.1 General
7.2.1.2 Liquid adhesives for paper and wood
134 7.2.1.3 Adhesive sticks and pastes for paper
135 7.2.2 Solvent-based adhesives
7.2.2.1 General
7.2.2.2 Multi-purpose adhesives
7.2.2.3 Contact adhesives
136 7.2.2.4 Special adhesives
137 7.2.2.5 Packaging
7.2.2.6 Marking
7.2.2.7 First aid information
138 7.2.2.8 Safety rules
7.3 Water-based paints or lacquers
7.3.1 General
7.3.2 Packaging
7.3.3 Marking
139 7.3.4 First aid information
7.3.5 Safety rules
7.4 Solvent-based paints, lacquers, thinners and cleaning solvents
7.4.1 General
140 7.4.2 Packaging
7.4.3 Marking
7.4.4 First aid information
141 7.4.5 Safety rules
8 Marking
8.1 General
8.2 Marking of the primary packaging
8.2.1 General
8.2.2 Manufacturer’s identification
8.2.3 Warning phrases
142 8.3 Marking of individual containers and any packagings
9 Instructions for use
9.1 General
9.2 Contents list
9.3 Advice for adult supervision
143 9.4 Safety rules
9.5 Instructions for carrying out the activities
9.6 Spills and disposal of chemicals
144 10 Test methods
10.1 General
10.2 Determination of plasticisers in oven-hardening polyvinyl chloride (PVC) modelling clay sets
10.2.1 Principle
10.2.2 Standards and reagents
10.2.2.1 Standards
145 10.2.2.2 Reagents
10.2.3 Apparatus
146 10.2.4 Preparation of standard solutions
10.2.4.1 Stock solutions
147 10.2.4.2 Calibration solutions
10.2.4.3 Stability of standard solutions
10.2.5 Sampling
148 10.2.6 Sample preparation
10.2.7 Procedure
10.2.7.1 General
10.2.7.2 Extraction of citric acid esters and alkylsulfonic acid esters
10.2.7.3 Extraction of adipic acid polyesters
10.2.7.4 Evaporation of the solvent and weighing
149 10.2.7.5 Blank determination
10.2.7.6 GC-MSD determination of citric acid esters and alkylsulfonic acid esters
10.2.7.7 ATR-FT-IR identification of adipic acid polyesters
10.2.8 Evaluation of results
10.2.8.1 Calculation of solvent-extractable content containing plasticisers
150 10.2.8.2 Calculation and identification of plasticiser content by GC-MS analysis
151 10.2.9 Test report
10.3 Determination of the emission of benzene, toluene and xylenes from oven-hardening plasticised PVC modelling clay sets and polystyrene granules sets
10.3.1 Principle
152 10.3.2 Standards and reagents
10.3.3 Apparatus
10.3.3.1 Gas chromatograph with mass spectrometer detector (GC-MS)
153 10.3.3.2 Headspace analysis conditions
10.3.3.3 Other laboratory equipment
154 10.3.4 Preparation of standard solutions
10.3.5 Sampling
10.3.6 Sample preparation
10.3.7 Procedure
10.3.8 Evaluation of results
155 10.3.9 Test report
10.3.10 Critical control points
10.4 Determination of styrene content in polystyrene granules
10.4.1 Principle
10.4.2 Standards and reagents
10.4.2.1 Standards
156 10.4.2.2 Reagents
10.4.3 Apparatus
157 10.4.4 Preparation of the standard solutions
10.4.5 Sampling
10.4.6 Sample preparation
10.4.7 Procedure
10.4.8 Evaluation of results
10.4.9 Test report
158 10.5 Determination of organic solvents
10.5.1 General
160 10.5.2 Principle
161 10.5.3 Standards and reagents
10.5.3.1 Standards
162 10.5.3.2 Reagents
10.5.4 Apparatus
164 10.5.5 Preparation of the standard solutions
10.5.5.1 Stock solutions for the identification and determination of solvents using HS-GC-FID
165 10.5.5.2 Stock solutions for the identification and determination of solvents using GC-MS
166 10.5.5.3 Stock solution for the identification and determination of propane-1,2-diol
10.5.5.4 Calibration solutions
171 10.5.6 Sampling
10.5.7 Sample preparation
10.5.7.1 General
172 10.5.7.2 Sample preparation for identification and determination of solvents by HS-GC-FID
10.5.7.3 Sample preparation for identification of solvents by GC-MS
10.5.7.4 Sample preparation for determination of certain solvents by GC-MS
173 10.5.7.5 Sample preparation for determination of propane-1,2-diol using GC-FID
10.5.8 Procedure
10.5.8.1 Identification of solvents using HS-GC-FID
176 10.5.8.2 Identification of solvents using GC-MS
177 10.5.8.3 Determination of solvent content by HS-GC-FID
178 10.5.8.4 Determination of solvent content using GC-MS
10.5.8.5 Determination of propane-1,2-diol by GC-FID
10.5.8.6 Blank determination
10.5.9 Evaluation of results
10.5.9.1 Calculation of solvent content by HS-GC-FID
179 10.5.9.2 Calculation of solvent content by GC-MS or GC-FID
10.5.10 Test report
10.6 Combined approach for the determination of plasticisers in solvent-based adhesives and in solvent-based paints or lacquers, film-forming agents in paints and lacquers and modifiers in solvent-based paints or lacquers
10.6.1 Principle
180 10.6.2 Determination of total extract
10.6.2.1 Standards and reagents
10.6.2.2 Apparatus
10.6.2.3 Sampling
10.6.2.4 Sample preparation
181 10.6.2.5 Procedure
10.6.2.6 Evaluation of results
10.6.3 Identification of nitrocellulose
10.6.3.1 Principle
10.6.3.2 Reagents
10.6.3.3 Apparatus
182 10.6.3.4 Sampling
10.6.3.5 Sample preparation
10.6.3.6 Procedure
10.6.3.7 Evaluation of results
183 10.6.4 Determination of plasticisers
10.6.4.1 Principle
10.6.4.2 Standards and reagents
10.6.4.3 Apparatus
10.6.4.4 Preparation of the standard solution
10.6.4.5 Procedure
10.6.4.6 Evaluation of results
10.6.5 Determination of film-forming agents
10.6.5.1 Principle
184 10.6.5.2 Standards and reagents
10.6.5.3 Apparatus
187 10.6.5.4 Preparation of standard solutions
188 10.6.5.5 Sampling
10.6.5.6 Procedure
10.6.5.7 Evaluation of results
189 10.6.6 Determination of the modifiers
10.6.7 Test report
BS EN 71-5:2015 - TC
$280.87