BS EN 71-5:2015 – TC:2020 Edition
$280.87
Tracked Changes. Safety of toys – Chemical toys (sets) other than experimental sets
Published By | Publication Date | Number of Pages |
BSI | 2020 | 200 |
This European Standard specifies requirements and test methods for the substances and materials used in chemical toys (sets) other than experimental sets. These substances and mixtures are: ? those classified as dangerous by the EC-legislation applying to dangerous substances and dangerous mixtures [5]; ? substances and mixtures which in excessive amounts could harm the health of the children using them and which are not classified as dangerous by the above mentioned legislation; and ? any other chemical substance(s) and mixture(s) delivered with the chemical toy. NOTE The terms “substance” and “ mixture” are defined in the REACH regulation No. (EC)1907/2006 and in the CLP regulation (EC) No. 1272/2008. Additionally, requirements are specified for markings, warnings, safety rules, contents list, instructions for use and first aid information. This Part of EN 71 applies to: ? plaster of Paris (gypsum) moulding sets; ? ceramic and vitreous enamelling materials supplied in miniature workshop sets; ? oven-hardening plasticised PVC modelling clay sets; ? plastic moulding sets; ? embedding sets; ? adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents), supplied or recommended in model sets.
PDF Catalog
PDF Pages | PDF Title |
---|---|
126 | 1 Scope 2 Normative references |
127 | 3 Terms and definitions |
128 | 4 Plaster of Paris (gypsum) moulding sets 4.1 Marking 4.2 First aid information 4.3 Safety rules |
129 | 5 Oven-hardening plasticised PVC modelling clay sets 5.1 Chemical substances 5.2 Marking 5.3 First aid information |
130 | 5.4 Safety rules 6 Moulding sets 6.1 Polystyrene granules sets 6.1.1 Chemical substances 6.1.2 Marking 6.1.3 First aid information |
131 | 6.1.4 Safety rules 6.2 Embedding sets 6.2.1 General 6.2.2 Packaging 6.2.3 Marking 6.2.4 First aid information 6.2.5 Safety rules |
132 | 7 Adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) supplied or recommended in model sets 7.1 General 7.2 Adhesives 7.2.1 Water-based adhesives 7.2.1.1 General 7.2.1.2 Liquid adhesives for paper and wood |
134 | 7.2.1.3 Adhesive sticks and pastes for paper |
135 | 7.2.2 Solvent-based adhesives 7.2.2.1 General 7.2.2.2 Multi-purpose adhesives 7.2.2.3 Contact adhesives |
136 | 7.2.2.4 Special adhesives |
137 | 7.2.2.5 Packaging 7.2.2.6 Marking 7.2.2.7 First aid information |
138 | 7.2.2.8 Safety rules 7.3 Water-based paints or lacquers 7.3.1 General 7.3.2 Packaging 7.3.3 Marking |
139 | 7.3.4 First aid information 7.3.5 Safety rules 7.4 Solvent-based paints, lacquers, thinners and cleaning solvents 7.4.1 General |
140 | 7.4.2 Packaging 7.4.3 Marking 7.4.4 First aid information |
141 | 7.4.5 Safety rules 8 Marking 8.1 General 8.2 Marking of the primary packaging 8.2.1 General 8.2.2 Manufacturer’s identification 8.2.3 Warning phrases |
142 | 8.3 Marking of individual containers and any packagings 9 Instructions for use 9.1 General 9.2 Contents list 9.3 Advice for adult supervision |
143 | 9.4 Safety rules 9.5 Instructions for carrying out the activities 9.6 Spills and disposal of chemicals |
144 | 10 Test methods 10.1 General 10.2 Determination of plasticisers in oven-hardening polyvinyl chloride (PVC) modelling clay sets 10.2.1 Principle 10.2.2 Standards and reagents 10.2.2.1 Standards |
145 | 10.2.2.2 Reagents 10.2.3 Apparatus |
146 | 10.2.4 Preparation of standard solutions 10.2.4.1 Stock solutions |
147 | 10.2.4.2 Calibration solutions 10.2.4.3 Stability of standard solutions 10.2.5 Sampling |
148 | 10.2.6 Sample preparation 10.2.7 Procedure 10.2.7.1 General 10.2.7.2 Extraction of citric acid esters and alkylsulfonic acid esters 10.2.7.3 Extraction of adipic acid polyesters 10.2.7.4 Evaporation of the solvent and weighing |
149 | 10.2.7.5 Blank determination 10.2.7.6 GC-MSD determination of citric acid esters and alkylsulfonic acid esters 10.2.7.7 ATR-FT-IR identification of adipic acid polyesters 10.2.8 Evaluation of results 10.2.8.1 Calculation of solvent-extractable content containing plasticisers |
150 | 10.2.8.2 Calculation and identification of plasticiser content by GC-MS analysis |
151 | 10.2.9 Test report 10.3 Determination of the emission of benzene, toluene and xylenes from oven-hardening plasticised PVC modelling clay sets and polystyrene granules sets 10.3.1 Principle |
152 | 10.3.2 Standards and reagents 10.3.3 Apparatus 10.3.3.1 Gas chromatograph with mass spectrometer detector (GC-MS) |
153 | 10.3.3.2 Headspace analysis conditions 10.3.3.3 Other laboratory equipment |
154 | 10.3.4 Preparation of standard solutions 10.3.5 Sampling 10.3.6 Sample preparation 10.3.7 Procedure 10.3.8 Evaluation of results |
155 | 10.3.9 Test report 10.3.10 Critical control points 10.4 Determination of styrene content in polystyrene granules 10.4.1 Principle 10.4.2 Standards and reagents 10.4.2.1 Standards |
156 | 10.4.2.2 Reagents 10.4.3 Apparatus |
157 | 10.4.4 Preparation of the standard solutions 10.4.5 Sampling 10.4.6 Sample preparation 10.4.7 Procedure 10.4.8 Evaluation of results 10.4.9 Test report |
158 | 10.5 Determination of organic solvents 10.5.1 General |
160 | 10.5.2 Principle |
161 | 10.5.3 Standards and reagents 10.5.3.1 Standards |
162 | 10.5.3.2 Reagents 10.5.4 Apparatus |
164 | 10.5.5 Preparation of the standard solutions 10.5.5.1 Stock solutions for the identification and determination of solvents using HS-GC-FID |
165 | 10.5.5.2 Stock solutions for the identification and determination of solvents using GC-MS |
166 | 10.5.5.3 Stock solution for the identification and determination of propane-1,2-diol 10.5.5.4 Calibration solutions |
171 | 10.5.6 Sampling 10.5.7 Sample preparation 10.5.7.1 General |
172 | 10.5.7.2 Sample preparation for identification and determination of solvents by HS-GC-FID 10.5.7.3 Sample preparation for identification of solvents by GC-MS 10.5.7.4 Sample preparation for determination of certain solvents by GC-MS |
173 | 10.5.7.5 Sample preparation for determination of propane-1,2-diol using GC-FID 10.5.8 Procedure 10.5.8.1 Identification of solvents using HS-GC-FID |
176 | 10.5.8.2 Identification of solvents using GC-MS |
177 | 10.5.8.3 Determination of solvent content by HS-GC-FID |
178 | 10.5.8.4 Determination of solvent content using GC-MS 10.5.8.5 Determination of propane-1,2-diol by GC-FID 10.5.8.6 Blank determination 10.5.9 Evaluation of results 10.5.9.1 Calculation of solvent content by HS-GC-FID |
179 | 10.5.9.2 Calculation of solvent content by GC-MS or GC-FID 10.5.10 Test report 10.6 Combined approach for the determination of plasticisers in solvent-based adhesives and in solvent-based paints or lacquers, film-forming agents in paints and lacquers and modifiers in solvent-based paints or lacquers 10.6.1 Principle |
180 | 10.6.2 Determination of total extract 10.6.2.1 Standards and reagents 10.6.2.2 Apparatus 10.6.2.3 Sampling 10.6.2.4 Sample preparation |
181 | 10.6.2.5 Procedure 10.6.2.6 Evaluation of results 10.6.3 Identification of nitrocellulose 10.6.3.1 Principle 10.6.3.2 Reagents 10.6.3.3 Apparatus |
182 | 10.6.3.4 Sampling 10.6.3.5 Sample preparation 10.6.3.6 Procedure 10.6.3.7 Evaluation of results |
183 | 10.6.4 Determination of plasticisers 10.6.4.1 Principle 10.6.4.2 Standards and reagents 10.6.4.3 Apparatus 10.6.4.4 Preparation of the standard solution 10.6.4.5 Procedure 10.6.4.6 Evaluation of results 10.6.5 Determination of film-forming agents 10.6.5.1 Principle |
184 | 10.6.5.2 Standards and reagents 10.6.5.3 Apparatus |
187 | 10.6.5.4 Preparation of standard solutions |
188 | 10.6.5.5 Sampling 10.6.5.6 Procedure 10.6.5.7 Evaluation of results |
189 | 10.6.6 Determination of the modifiers 10.6.7 Test report |